Hello Jack, welcome to the forum..
please take this the way it is intended..
I am sure you are more than capable to physically install the cables switchgear connect & test it to make sure its safe..
BUT you do seem to be lacking a bit of BASIC electrical science.
e.g. the total load of an oven is NOT all of the bits added up together.
Because in practice no one has every ring all the oven(s) and the Grill(s) ALL switched on to max SIMULTANEOUSLY.
This is what Theory was trying to explain about diversity.
Also with the CU ALL circuits are NOT running full power all of the time!
DO you have any regs books?
you may find it helpfull to have a read of 'Maximum demand and diversity'..
which can be found in
Appendix 1, Page 95 On site guide.
or
Appendix H, Page 177 Guidance Note 1.
Which is why the info you had said 2.5mm may be ok?
are there two ovens with thier own connecting lead from the back
or just one cable connection?
Also if it is a long run from CU to cooker issues of permissible volt drop may need to be taken account of as well.
The other point you should take account if is that a new cooker circuit comes within the remit of Part B building regulations.
OOPS!Blushing Part P building regulations (thank you ian932:| :x
so it should have a Building regs compliance certificate issued AS WELL as an electrical installation certificate.
An electrician registered with one of the approved scheme providers can self certify their work..
Otherwise you should notify the LABC first (bit like planing permission or an extension!)
Details of Part P building regs can be found in Approved document P.
Electrical safety in dwellings.
There's a link on the site somewhere to a copy that you can download!