PSSC and PEFC will differ except when taken at the CCU with main earth disconnected, because of parallel earth paths. Testing L-N the current can use those conductors to get back to the supply the supply transformer, L-E can go via the CPC to the CCU but from the CCU can also go via anything you have main bonding to. So PEFC should be higher from somewhere on the circuit.
At least this is what I think is correct, happy to be corrected if it's not.
Agree with the other comments on the variation in readings. How hard you press with the probes can change the reading that much. If you use crocodile clips or something that doesn't require you to hold it in place it's more likely to be exactly the same, but for 0.01ohms, there's not much point.