It sounds as if the heating system has multiple supplies - possibly on different RCBO's etc. It's a recipe for problems.
Pick one supply point and test it properly (properly = not just with a high impedance voltmeter or a neon etc.)
Then connect the controller to it and see what happen on the outputs
If OK run supplies from the same point to the boiler and test that (with a link to fire up if you cant find a test mode).
If that's ok it should all work as expected when the controller is connected to the boiler
Pick one supply point and test it properly (properly = not just with a high impedance voltmeter or a neon etc.)
Then connect the controller to it and see what happen on the outputs
If OK run supplies from the same point to the boiler and test that (with a link to fire up if you cant find a test mode).
If that's ok it should all work as expected when the controller is connected to the boiler
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