Take a look on the back of the Programmer that goes onto the base, it should have a wiring diagram as to what terminal is what.
With 3 switching cores ( 3 cre + e cable) then you normally would have CH on, HW on and HW off used.
You really need to know whats at the other end of that 3 CRE + e cable.
Is there a wiring centre/ junction box near the cylinder?
The HW on terminal on your base would normally feed a Room stat and the HW on and off terminals link with a cylinder stat via a wiring ctr/juction box.