The op has had the boiler replaced with a combi so no need for a water valve..
He was just trying to utilise what was already there rather than the expense of modifying pipes and buying more valves...
when with just a bit of wiring he should be able to get what he wants..
i.e. two zones controlled from an existing 3port valve!
it isn't that difficult to do.
.
3 port valves are designed to be used for heating and hot water, and need a Hot water OFF signal to work.
No doubt you could get one to work with two heating zones instead, but that would mean one zone would need to provide a "Heating off" signal.
I doubt you will find an UFH manifold controller that provides a heating off signal. So you can't use the HW output of the 3 port valve for the UFH side.
So if you used the HW port of the 3 port valve for the radiators (and the heating port for the UFH) you might be able to get it to work as you can usually get a heating off signal from the programmer for that for the radiators. But if you have a room thermostat for the radiators you would have to get one with a changeover contact (same as the HW thermostat is a changeover contact), which might be tricky.
I would hardly say for a novice that it wasn't tricky to do.
for a little bit of plumbing two 2 port valves would give a better solution. but that's just my opinion.
you would need to start by drawing a circuit diagram including all the components including programmers, UFH manifold controllers, thermostats etc.
EDIT
Just read more of the thread. Seems like many people before me have told you to ditch the 3 port and fit two 2 port valves. Looking at your picture, it's a pretty simple swap to do that, you have plenty of space and it will take a plumber about an hour I would guess, a bit more allowing for draining and re filling.
What's that thing with a flow meter built in between the flow and return?
And I haven't seen the quesion answered so I'll ask it again, is there a mixer valve anywhere to reduce the flow temperature to the UFH pipes?