Sorry not to have replied to all your posts sooner - I've had a mental couple of days in work and haven't even been near a laptop. Anyway, thank you all again for your time and efforts. It is very difficult at times, as I'm sure you'll appreciate, to communicate quite what I'm seeing/experiencing with the issue and, likewise, for people to advise based on that info.
Anyway, suffice to say I have now checked and double checked every element/component of the system and ruled out any faults in that sense and, through all my digging/research (the internet is a wonderful thing!) and all the help on here, I have actually become quite au fait with how it works.
I finally bit the bullet this morning and took the advice of a colleague who, like yourself batty, suggested stripping it all out in the junction box and wiring it back in from scratch and........Success! I then got my colleague to pop out at lunch with me to double check everything and basically get some reassurance that all was as it should be and that the actuator was all switching over correctly for heat, water and both etc. etc.
The programmer is linked, (you are right again batty!) through L-5-8. What the main problem with it all seemed to be (apart from some other wiring errors upstairs in the junction box) was that the spur from the programmer carrying the L/N/E up to the junction box wasn't connected on the live. This only became apparent this morning when I decided to totally unscrew the backplate and inspect everything coming in/out. Perhaps I should have done this before now but, looking at it as I was, it appeared that I had full view of everything in there. Why it was like this, who knows?? but it answered my question as to why I wasn't picking up a Live at the other end.
There were a few other issues like the cylinder stat being wired up arse-about-face and there needing to be wiring for a pump overrun, but I think everything else was already as it should've been.
This issue has plagued me for what feels like an eternity, but I'm glad to say that I will sleep well tonight. Sadly no beer to help me on my way - I'll save that for the weekend!!
Thank you all once again, though. I am sincerely very thankful and Would like to say how good it is to know there are people out there willing to give their time and help to amateurs like myself. Big thumbs up!! :Applaud :Applaud :Applaud