as far as we are aware, everything was unplugged / disconnected. Would a neon cause earth leakage, surely they would only affect reading L - N not (L+N) - CPC
A neon will not normally trip an RCD, even if wired across L-E...
Although they will give an unrealistic low insulation resistance test reading...
With this sort of problem you have to stop and step back and think about exactly what you are reading and what is and ins not acceptable in the regs...
If all test readings are acceptable to the regs then the wiring will Not be causing any RCD trips..
and if the RCD tests are within the tolerance specified by the regs then the RCD will not be giving nuisance trips..
If trips continue to occur there is either a faulty appliance or group of faulty appliances..
Or a selection of equipment with natural leakage to earth that when combined can exceed the RCD tolerance..
Some ovens specifically state they should NOT be connected via an RCD do to some natural leakage..
Don't get mixed up with your numbers when testing...
Remember... Page 191 table 61
Minimum Ins Res 1.0meg or 1,000,000ohms or 0.00023amp acceptable
RCD must not trip @ 15ma or 0.015A or 15333.33ohms should Not trip RCD..
RCD must trip @ 30ma or 0.03A or 7666.66ohms MUST trip RCD..
The average Neon (go do an Ins Res across a lead with a neon socket attached) will give around
0.25Meg or 250,000ohms To 0.30Meg or 300,000ohms
So these neons would show as a too low Ins res reading... But are still to high for tripping an RCD.
Some of those illuminated light switches have neons wired from L to E.. (as no N @ switch)
Did you double check both ways on two-way light switching when doing your Ins Res tests?
My gut feeling is something involving water...
Central heating pumps valves etc..
Immersion heaters
Steam Irons
Washing machines / Dishwashers (outlet pipes blocked causing back flow across electrics)
Cordless kettle bases
etc....
either way even if the RCD is operating all OK
as a single mains switch RCD the installation does not comply with 314 page 46!