Bare in mind that reading the voltage on the inverter like this is NOT Voc. 'in circuit' voltage which will always be lower that open cicuit voltage.
Not sure about that particular inverter but some inverters you can turn the AC supply off and the inverter is still live and you will get a voltage a bit closer to Voc.
Is 1 string in the sun and 1 out the sun? temperature tends to affect voltage, panels don't like to be hot. That could explain the different string voltages.
The only real way to get the right number is to open the circuit, but you can only really do this if you are compentent to do so. i.e turn off dc isolator, then either a) open DC isolator and test incoming cables at the terminals or 2) disconnect DC plugs from inverter, connect test leads to then and turn DC iso back on.
DO NOT disconnect the plugs under load without turn isolators off first.
Also note, DC power stings quite a bit and is more dangerous than AC. So, if you decide to faff, please be very careful.